In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application. 相似文献
We analyzed the spatial local accuracy of land cover (LC) datasets for the Qiangtang Plateau, High Asia, incorporating 923 field sampling points and seven LC compilations including the International Geosphere Biosphere Programme Data and Information System (IGBPDIS), Global Land cover mapping at 30 m resolution (GlobeLand30), MODIS Land Cover Type product (MCD12Q1), Climate Change Initiative Land Cover (CCI-LC), Global Land Cover 2000 (GLC2000), University of Maryland (UMD), and GlobCover 2009 (Glob-Cover). We initially compared resultant similarities and differences in both area and spatial patterns and analyzed inherent relationships with data sources. We then applied a geographically weighted regression (GWR) approach to predict local accuracy variation. The results of this study reveal that distinct differences, even inverse time series trends, in LC data between CCI-LC and MCD12Q1 were present between 2001 and 2015, with the exception of category areal discordance between the seven datasets. We also show a series of evident discrepancies amongst the LC datasets sampled here in terms of spatial patterns, that is, high spatial congruence is mainly seen in the homogeneous southeastern region of the study area while a low degree of spatial congruence is widely distributed across heterogeneous northwestern and northeastern regions. The overall combined spatial accuracy of the seven LC datasets considered here is less than 70%, and the GlobeLand30 and CCI-LC datasets exhibit higher local accuracy than their counterparts, yielding maximum overall accuracy (OA) values of 77.39% and 61.43%, respectively. Finally, 5.63% of this area is characterized by both high assessment and accuracy (HH) values, mainly located in central and eastern regions of the Qiangtang Plateau, while most low accuracy regions are found in northern, northeastern, and western regions.
